A new criterion to decide whether the carboxy group coordinating to the metallic ion in mono or bi dentate-fashion in an ambiguous situation, base on coordination bond distances and angles.
通过上述晶体结构中配位键长键角的分析,得到了一个行之有效的标准,判断羧基与中心金属离子是单齿配位还是螯合配位。
Results of analysis with IR and ESCA showed that ring -shaped conjugated structures exist in the films. Copper atom may be linked to the polymer either by covalent bond or coordination bond.
红外光谱和电子能谱的分析结果表明:聚合物薄膜中含有环状共轭结构,铜与聚合物以共 价键、配 位键结合。
Results of analysis with IR and ESCA showed that ring -shaped conjugated structures exist in the films. Copper atom may be linked to the polymer either by covalent bond or coordination bond.
红外光谱和电子能谱的分析结果表明:聚合物薄膜中含有环状共轭结构,铜与聚合物以共 价键、配 位键结合。
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