We talked about this reaction here, where we had chloride ion in the gas phase plus sodium ion in the gas phase.
我们在讨论这一个反应，气态的氯原子加上气态的钠原子。
The linear relationship between the gas phase standard enthalpies of formation and the substituent constants is discussed.
讨论了气态摩尔标准生成焓与取代基常数间的线性关系。
Dalton only deals with what's happening in the gas phase.
道尔顿只处理气相中的问题。
yB So in the gas phase, we've got mole fractions yA and yB.
所以在气相中，我们有摩尔分数yA和。
So, what happens if I put pluses and minuses in a gas phase?
如果我把带正电的东西和带负电的东西都放在，一个气相中，会是什么样呢？
This is called ionization, gas phase species loses an electron.
而这个过程是离子化，气相组分失去一个电子。
Basically, it's looking at decomposition of a gas phase molecule.
大体上，它是看气相分子的分解。
And this is just the Gibbs free energy per mole of a in the gas phase.
气相中的化学势，就是气相中每摩尔a的吉布斯自由能。
If you look at molecules moving around in the gas phase or in a liquid.
如果你看气相，或液相中分子的运动。
So that means that the molecules of CS2 would rather go in the gas phase.
这说明CS2分子2，更喜欢进入气相。
yB And yA and yB in the gas phase, the mole fractions in the gas phase.
在气体中是yA和，这是气体中的摩尔分数。
So I decrease the pressure, I get the pure gas phase of my new solution here.
因此我降压，可以得到一个完全是气相的新的溶液。
What's the composition of liquid, compared to the composition of the gas phase?
和气相成分比较，液体的成分是什么？
And I am saying suppose these form, as they have to initially, in the gas phase.
我想说假设这些形式，就和它们气相中的一样。
See, up until now I have been talking about gas phase, single atoms, all this stuff.
看，只到现在我们已经讨论了气相，单原子，这些东西。
And if we go over here, this is telling us about the mole fraction in the gas phase.
如果我们到达那，它告诉了我们气相的摩尔分数。
Let's consider a mole of atoms, roaming around in the gas phase at room temperature.
考虑一摩尔原子，这些原子处于室温下的气态。
We've found composition in the gas phase in terms of composition in the liquid phase.
我们已经用液相的组分，写出了气相的组分。
And we squeeze, and now we've got more water in the liquid phase than in the gas phase.
我们继续压缩，现在液态的水，比气态的水更多。
So I'm going to find the total pressure as a function of the composition in the gas phase.
我想找到总压强作为，气相中组分的函数。
So what that means is, relative to the ideal solution, they'd rather go up into the gas phase.
那意味着，相对于理想溶液，它们更愿意上升进入气相。
Going to make the same diagram, except now I'm going to use the gas phase as my reference point.
然后就可以做出相图了，唯一不同的是我这里用气相作为我的参考点。
And I know that should tell me immediately whether the composition in the gas phase is here.
我已经知道液相的组分在这里，我知道液体的组分之后。
Because really what we want is the total pressure as a function of the composition in the gas phase.
因为我们想要的是，总压强作为气相组分的函数。
So if you take them all from the liquid and put them all up into the gas phase, it must be the same.
所以如果把全部的，都从液态变成气态，它一定是相等的。
So I've gotten the composition in the gas phase in terms of the composition in the liquid phase.
我利用液体中的组分，表示出了气体中的组分。
In other words, they were there in the entropy contribution in the gas phase as well, in the pure gas.
换句话说，它们也对熵有贡献，在气相时在纯气体时。
So I have all, I have everything I need to know t o calculate what the composition in the gas phase is.
就能够很快算，出气相的组分，我现在知道所有的条件。
Chemical potentials of a, in the gas phase has to be the same as the chemical potential of a in the liquid phase.
处于气态的A的化学势等于，处于液态的A的化学势。
So I can draw a diagram that looks just like this except now with the X-axis being the gas phase composition.
这样我就可以做一个，和这个相似的相图，唯一不同之处就在于x轴代表气体组分比。
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