综述了近年来联萘衍生物作为手性配体构成的金属络合物在前手性烯、酮及亚胺的不对称氢化反应中的应用。
In this article, the recent application in recent years of metal complexes composed of binaphthyl derivatives in asymmetric hydrogenation of prochiral alkenes, ketones and imines are reviewed.
另外，还讨论了反应的金属氢化物机理，并获得了支持该机理存在的间接证据。
In addition, it was presumed that the dimerization reaction was attributed to the metal hydride mechanism, and some indirect evidences were obtained for supporting this mechanism.
对近年来过渡金属络合物对酮类化合物不对称催化氢化反应研究进展进行了综述。
The recent progress of the ketones in catalytic asymmetric hydrogenation is reviewed in this paper.
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