Anderson then told the southerners, "If you do not shell us to pieces, hunger will force us out in a few days."

VOA: special.2009.08.06

In other words, just want to know where the electron is somewhere within the shell radius of the ground state of atomic hydrogen anywhere.

换言之，我只是想知道,电子在哪,可以在氢原子基态下的半径,里面的任何地方。

麻省理工公开课 - 固态化学导论课程节选

But still, when we're talking about the radial probability distribution, what we actually want to think about is what's the probability of finding the electron in that shell?

但当我们讲到径向概率分布时,我们想做的是考虑，在某一个壳层里,找到电子的概率,就把它想成是蛋壳？

麻省理工公开课 - 化学原理课程节选

Founding partners in the alliance include governments and United Nations agencies,nonprofit groups and the energy company Shell.

VOA: special.2010.09.27

There is a huge difference between the energies in the outermost shell and the inner shells, which tells you that it's unlikely that any electrons except those in the outermost shell are going to be active.

最外层和最里层所具有的能量,有很大差异，而这告诉我们有一点是不太可能的,那就是除了最外层的电子,别的电子都是应该是活泼的。

麻省理工公开课 - 固态化学导论课程节选

So. Starting with the shell, I can type in expressions.

好，从sell开始，我可以输入一些表达式。

麻省理工公开课 - 计算机科学及编程导论课程节选

So the 3 s 1, or any of the other electrons that are in the outer-most shell, those are what we call our valence electrons, and those are where all the excitement happens.

它们是经常发生激发情况的,那也是我们所看到，我们称之为价电子，它们是经常发生激发情况的。

麻省理工公开课 - 化学原理课程节选

We're saying the probability of from the nucleus in some very thin shell that we describe by d r.

某一非常薄的壳层dr内,一个原子的概率,你想一个壳层时。

麻省理工公开课 - 化学原理课程节选

They have the highest average valence electron energy in any shell.

它们有最大的价电子能,任意一层都是这样。

麻省理工公开课 - 固态化学导论课程节选

So here we're talking about v plus 1, so if we were to write it just for the neutral electron itself, we would find that the electron configuration is argon, that's the filled shell in front of it.

这里我们要分析的是正一价的钒离子，因此，我们先写出中性原子的电子排布，可以发现，其原子实是氩原子的电子排布，这些壳层已经被占满了。

麻省理工公开课 - 化学原理课程节选

N so, we've got five electrons here in the valence shell.

是1s2，2s2，2p3，Nitrogen，is，1s2，，2s2，，2p3，因此，有5个价层电子。

麻省理工公开课 - 固态化学导论课程节选

Whatever the n number is, with the exception of helium, helium is the oddity because there's only two elements in n equals one shell.

无论n是多少，除了氦之外，氦是个特例,因为只有两个元素,在n为1的这一层。

麻省理工公开课 - 固态化学导论课程节选

All in all, in the l shell, I have the possibility of eight different configurations.

所以总的来说，在L层,总共可能有八种不同构型。

麻省理工公开课 - 固态化学导论课程节选

So there are two electron configurations in the n equals one shell, if we follow according to the selection rules that we spelled out last day.

如果根据上次课,我们阐明的原子光谱选择定则，我们就会知道在n等于1的那一层,有两种电子图像构型。

麻省理工公开课 - 固态化学导论课程节选

Core electrons are all those electrons held in really tight with the nucleus in the inner shells, whereas the valence electrons are only those electrons that are in the outer-most shell, or at your highest value of n of the principal quantum number.

芯电子是那些,在内壳层被原子核束缚得非常紧的电子，而价电子只包括,最外层的电子，或者说主量子数，n，的值最大的那些电子。

麻省理工公开课 - 化学原理课程节选

So let's do a quick clicker question, and you tell me how many valence electrons does fluorine have? Remember, valence electrons are different from core, they're only the outer-most electrons in the outer-most shell.

那么让我们来做一个小选择题，请大家来告诉我,氟有多少个价电子，要记得，价电子与芯电子不同，它们是在最外壳层的最靠外面的电子。

麻省理工公开课 - 化学原理课程节选

So, let's take a look at one of these rows in more detail to think about why this might be happening, and it turns out the reason that these glitches occur are because the sub shell structure predominates in certain instances, and that's where these glitches take place.

那么，让我们仔细地看一看其中一行,想一想为什么会这样，结果是这些小偏差的出现,是因为在一定情况下,亚壳层结构会产生重要影响，这正发生在小偏差出现的地方。

麻省理工公开课 - 化学原理课程节选

r And what that is the probability of finding an electron in some shell where we define the thickness as d r, some distance, r, from the nucleus.

在某个位置为,厚度为dr的壳层内,找到原子,的概率，我们来考虑下我们这里所说的。

麻省理工公开课 - 化学原理课程节选

The other main difference that we're really going to get to today is that in multi-electron atoms, orbital energies depend not just on the shell, which is what we saw before, not just on the value of n, but also on the angular momentum quantum l number. So they also depend on the sub-shell or l.

我们今天要讨论的,另一个很重要的区别就是,在多电子原子中，轨道能力不仅仅依赖于，我们以前看到的外层，不仅仅依赖于n的值，而是与角动量量子数也有关系,所以它们也依赖于亚外层或者。

麻省理工公开课 - 化学原理课程节选

s But it just turns out that the 4 s is so low in energy that it actually surpasses the 3 d, because we know the 3 d is going to be pretty high in terms of the three shell, and the 4 s is going to be the lowest interms of the 4 shell, and it turns out that we need to fill up the 4 s 4s before we fill in the 3 d.

但是结果是,能量较低,4s是第四层最低的，因为我们知道3d在第三层,是非常高的，4s是第四层,最低的，结果是我们在填充3d之前,需要先填充。

麻省理工公开课 - 化学原理课程节选